Battery Heated Boot Sock
When you say you've tried "toe warmers," do you mean the chemical models? Have you tried the Heat Treat-brand of toe warmers? These consist of little pouches that heat to 100 degrees once exposed to air. Regular price is $82 for 40 pairs (www.grabberwarmers.com), though you can buy smaller boxes, too.
You could make your boots warmer. Replace the stock insoles, for instance, with a pair of Insolator Winter Insoles ($8 at Campmor, www.campmor.com), which add an insulated later beneath your foot to help reduce the cold that's invariably conducted into the boots by your ski bindings. And of course, good socks help a lot. You might try Lange ThermaStat Silk Socks ($30, www.snowshack.com), a very thin ski-specific sock that uses hollow synthetic fibers along with silk to make a warm sock that isn't bulky. You also could buy silk sock liners ($10 at Lands' End, www.landsend.com), and over that wear a pair of SmartWool Ski Socks ($19, www.smartwool.com).
As a last resort, check the fit of your boot. Boots that are too tight can restrict circulation to your feet, making your feet cold. But I think tinkering with your socks will solve the problem.